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Recyclable Metal Air Fuel Cells Using Sintered Magnesium Paste with Reduced Mg Nanoparticles by High-Repetitive Ns Pulse Laser Ablation in Liquid

Received: 27 November 2014     Accepted: 3 December 2014     Published: 5 December 2014
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Abstract

An energy cycle using solar power and metals has been proposed. High repetitive laser pulses are generated by a solar-pumped laser or a laser generated using solar power, and the laser pulses are irradiated to metal oxides in liquid. We can obtain reduced metal nanoparticles with this method, and solar power is effectively stored as chemical energy. We succeeded in producing sintered Mg metal paste. The sintered Mg nanopaste reduced Mg nanoparticles from pure MgO or Mg(OH)2 powder, collected from used Mg air cells, by laser ablation in liquid using a high-repetitive ns pulse Nd:YAG laser. We also fabricated metal air fuel cells using sintered Mg plates as negative electrodes. Electricity was successfully produced from these cells. A light-emitting diode and a motor were connected to the Mg paste air fuel cells and the output voltage and current of the cells were measured. The observed output voltage was 1.4 V when they were connected to a low load, which is the same as conventional Mg air cells. Metal oxides were reduced with high efficiency and at a noticeably low cost by using lasers generated from solar energy. This makes it possible to recycle Mg plates. The new recyclable Mg paste air fuel cells are expected to become common power supplies with high-energy density and high output power.

Published in International Journal of Sustainable and Green Energy (Volume 3, Issue 6)
DOI 10.11648/j.ijrse.20140306.14
Page(s) 143-149
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Magnesium, Recycle, Solar Power, Solar-Pumped Pulse Laser, Laser Ablation in Liquid

References
[1] P. Charvin, S. Abanades, F. Lemort, and G. Flamant, “Hydrogen Production by Three-Step Solar Thermochemical Cycles Using Hydroxides and Metal Oxide Systems”, Energy & Fuels, vol. 21, pp. 2919-2928, July 2007.
[2] D. G. Rowe, “Solar-powered lasers”, Nature Photonics, vol. 4 pp.64-65, Feb. 2010.
[3] T. Yabe, T. Okubo, S. Uchida, K. Yoshida, M. Nakatuska, T. Funatsu, A. Mabuti, A. Oyama, K. Nakagawa, T. Oishi, K. Daito, “High-efficiency and economical solar-energy-pumped laser with Fresnel lens and chromium codoped laser medium”, Appl. Phys. Lett., vol. 90 pp.261120-261122, June 2007.
[4] M. S. Mohamed, T. Yabe, C. Baasandash, Y. Sato, Y. Mori, L. Shi-Hua, H. Sato, and S. Uchida, ”Laser- induced magnesium production from magnesium oxide using reducing agents”, J. Appl. Phys., vol. 104 pp.113110-113116, Dec. 2008.
[5] M. Weksler and J. Shwartz”, Solar-pumped solid-state lasers”, IEEE J. Quantum. Electron, vol. 24 pp.1222-1228, July 1988.
[6] T. Saiki, M. Nakatsuka, K. Imasaki, “Highly efficient lasing action of Nd3+- and Cr3+-doped yttrium aluminum garnet ceramics based on phonon-assisted cross-relaxation using solar light source”, Jpn. J. App. Phys., vol. 49 pp.082702-1-8, Aug. 2010.
[7] T. Saiki, M. Nakatsuka, K. Fujioka, S. Motokoshi, K. Imasaki, Y. Iida, “Increase in Effective Fluorescence Lifetime by Cross-Relaxation Effect Depending on Temperature of Nd/Cr:YAG Ceramic Using White-Light Pump Source”, Optics and Photonics Letters, vol 6 No.1 1350003-1-15, Apr. 2013.
[8] T. Saiki, T. Okada, K. Nakamura, T. Karita, Y. Nishikawa, Y. Iida, ”Air Cells Using Negative Metal Electrodes Fabricated by Sintering Pastes with Base Metal Nanoparticles”, International Journal of Energy Science, vol. 2 Iss. 6 pp.228-234, Dec. 2012.
[9] T. Okada, T. Saiki, S. Taniguchi, T. Ueda, K. Nakamura, Y. Nishikawa, and Y. Iida, "Hydrogen Production using Reduced-iron Nanoparticles by Laser Ablation in Liquids", ISRN Renewable Energy, vol. 2013 ID 827681-1-7, 2013.
[10] A. Henglein, “Physicochemical properties of small metal particles in solution: "microelectrode" reactions, chemisorption, composite metal particles, and the atom-to-metal transition”, J. Phys. Chem., vol. 97 pp.5457-5471, May 1993.
[11] M. S. Sibbald, G. humanov, and T. M. Cotton, “Reduction of cytochrome c by halide-modified, laser- ablated silver colloids”, J. Phys. Chem., vol. 100 pp.4672-4678, Mar. 1996.
[12] M. Kawasaki and N. Nishimura, ”Laser-induced fragmentative decomposition of ketone-suspended Ag2O micropowders to novel self-stabilized Ag nanoparticles”, J. Phys. Chem. C, vol. 112 pp.15647- 15655, Sep. 2008.
[13] H. Q. Wang,, A. Pyatenko, K. Kawaguchi, X. Y. Li , Z. Swiatkowska-Wackocka, and N. Koshizaki, ”Selective pulsed heating for the synthesis of semiconductor and metal submicrometer spheres”, Angew. Chem. Int. Ed., vol. 49 pp.6361-6364, Aug. 2010.
[14] K. Yamada, K. Miyajima, and F. Mafune, “Ionization of gold nanoparticles in solution by pulse laser excitation as studied by mass spectrometric detection of gold cluster ions”, J. Phys. Chem. C, vol. 111, pp.033401-1-4, July 2007.
[15] M. Shoji, K. Miyajima, and F. Mafune,”Ionization of gold nanoparticles in solution by pulse laser excitation as studied by mass spectrometric detection of gold cluster ions”, J. Phys. Chem. C, vol. 112 pp.1929-1932, Jan. 2008.
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Cite This Article
  • APA Style

    Taku Saiki, Shigeaki Uchida, Tatsuya Karita, Kazuhiro Nakamura, Yuusuke Nishikawa, et al. (2014). Recyclable Metal Air Fuel Cells Using Sintered Magnesium Paste with Reduced Mg Nanoparticles by High-Repetitive Ns Pulse Laser Ablation in Liquid. International Journal of Sustainable and Green Energy, 3(6), 143-149. https://doi.org/10.11648/j.ijrse.20140306.14

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    ACS Style

    Taku Saiki; Shigeaki Uchida; Tatsuya Karita; Kazuhiro Nakamura; Yuusuke Nishikawa, et al. Recyclable Metal Air Fuel Cells Using Sintered Magnesium Paste with Reduced Mg Nanoparticles by High-Repetitive Ns Pulse Laser Ablation in Liquid. Int. J. Sustain. Green Energy 2014, 3(6), 143-149. doi: 10.11648/j.ijrse.20140306.14

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    AMA Style

    Taku Saiki, Shigeaki Uchida, Tatsuya Karita, Kazuhiro Nakamura, Yuusuke Nishikawa, et al. Recyclable Metal Air Fuel Cells Using Sintered Magnesium Paste with Reduced Mg Nanoparticles by High-Repetitive Ns Pulse Laser Ablation in Liquid. Int J Sustain Green Energy. 2014;3(6):143-149. doi: 10.11648/j.ijrse.20140306.14

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  • @article{10.11648/j.ijrse.20140306.14,
      author = {Taku Saiki and Shigeaki Uchida and Tatsuya Karita and Kazuhiro Nakamura and Yuusuke Nishikawa and Shinji Taniguchi and Yukio Iida},
      title = {Recyclable Metal Air Fuel Cells Using Sintered Magnesium Paste with Reduced Mg Nanoparticles by High-Repetitive Ns Pulse Laser Ablation in Liquid},
      journal = {International Journal of Sustainable and Green Energy},
      volume = {3},
      number = {6},
      pages = {143-149},
      doi = {10.11648/j.ijrse.20140306.14},
      url = {https://doi.org/10.11648/j.ijrse.20140306.14},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijrse.20140306.14},
      abstract = {An energy cycle using solar power and metals has been proposed. High repetitive laser pulses are generated by a solar-pumped laser or a laser generated using solar power, and the laser pulses are irradiated to metal oxides in liquid. We can obtain reduced metal nanoparticles with this method, and solar power is effectively stored as chemical energy. We succeeded in producing sintered Mg metal paste. The sintered Mg nanopaste reduced Mg nanoparticles from pure MgO or Mg(OH)2 powder, collected from used Mg air cells, by laser ablation in liquid using a high-repetitive ns pulse Nd:YAG laser. We also fabricated metal air fuel cells using sintered Mg plates as negative electrodes. Electricity was successfully produced from these cells. A light-emitting diode and a motor were connected to the Mg paste air fuel cells and the output voltage and current of the cells were measured. The observed output voltage was 1.4 V when they were connected to a low load, which is the same as conventional Mg air cells. Metal oxides were reduced with high efficiency and at a noticeably low cost by using lasers generated from solar energy. This makes it possible to recycle Mg plates. The new recyclable Mg paste air fuel cells are expected to become common power supplies with high-energy density and high output power.},
     year = {2014}
    }
    

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  • TY  - JOUR
    T1  - Recyclable Metal Air Fuel Cells Using Sintered Magnesium Paste with Reduced Mg Nanoparticles by High-Repetitive Ns Pulse Laser Ablation in Liquid
    AU  - Taku Saiki
    AU  - Shigeaki Uchida
    AU  - Tatsuya Karita
    AU  - Kazuhiro Nakamura
    AU  - Yuusuke Nishikawa
    AU  - Shinji Taniguchi
    AU  - Yukio Iida
    Y1  - 2014/12/05
    PY  - 2014
    N1  - https://doi.org/10.11648/j.ijrse.20140306.14
    DO  - 10.11648/j.ijrse.20140306.14
    T2  - International Journal of Sustainable and Green Energy
    JF  - International Journal of Sustainable and Green Energy
    JO  - International Journal of Sustainable and Green Energy
    SP  - 143
    EP  - 149
    PB  - Science Publishing Group
    SN  - 2575-1549
    UR  - https://doi.org/10.11648/j.ijrse.20140306.14
    AB  - An energy cycle using solar power and metals has been proposed. High repetitive laser pulses are generated by a solar-pumped laser or a laser generated using solar power, and the laser pulses are irradiated to metal oxides in liquid. We can obtain reduced metal nanoparticles with this method, and solar power is effectively stored as chemical energy. We succeeded in producing sintered Mg metal paste. The sintered Mg nanopaste reduced Mg nanoparticles from pure MgO or Mg(OH)2 powder, collected from used Mg air cells, by laser ablation in liquid using a high-repetitive ns pulse Nd:YAG laser. We also fabricated metal air fuel cells using sintered Mg plates as negative electrodes. Electricity was successfully produced from these cells. A light-emitting diode and a motor were connected to the Mg paste air fuel cells and the output voltage and current of the cells were measured. The observed output voltage was 1.4 V when they were connected to a low load, which is the same as conventional Mg air cells. Metal oxides were reduced with high efficiency and at a noticeably low cost by using lasers generated from solar energy. This makes it possible to recycle Mg plates. The new recyclable Mg paste air fuel cells are expected to become common power supplies with high-energy density and high output power.
    VL  - 3
    IS  - 6
    ER  - 

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Author Information
  • Department of Electrical and Electronic Engineering, Faculty of Engineering Science, Kansai University, 3-3-35 Yamate, Suita, Japan

  • The Graduate School for the Creation of New Photonics Industries, 1955-1 Kurematsu-cho, Nishiku, Hamamatsu, Shizuoka, Japan

  • Department of Electrical and Electronic Engineering, Faculty of Engineering Science, Kansai University, 3-3-35 Yamate, Suita, Japan

  • Department of Electrical and Electronic Engineering, Faculty of Engineering Science, Kansai University, 3-3-35 Yamate, Suita, Japan

  • Department of Electrical and Electronic Engineering, Faculty of Engineering Science, Kansai University, 3-3-35 Yamate, Suita, Japan

  • Institute for Laser Technology, 1-8-4 Utsubo-honmachi, Nishi-ku, Osaka, Japan

  • Department of Electrical and Electronic Engineering, Faculty of Engineering Science, Kansai University, 3-3-35 Yamate, Suita, Japan

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